Using the ideal gas equation, the total number of moles of the mixture is given by:
n=RTPV
Substituting the given values:
P=100 kPa=105 Pa
V=8310 cm3=8.31×10−3 m3
T=300 K
R=8.31 J/(mol⋅K)
n=8.31×300105×8.31×10−3=300100=31 mol
Let n1 and n2 be the number of moles of CO2 and O2 respectively.
n1+n2=31
The total mass of the mixture is 13.2 g. Using the molar masses of CO2 (44 g/mol) and O2 (32 g/mol):
44n1+32n2=13.2
Substituting n2=31−n1 into the mass equation:
44n1+32(31−n1)=13.2
12n1+332=13.2
12n1=339.6−32=37.6
n1=367.6=9019≈0.21 mol
The number of moles of O2 is:
n2=31−9019=9011≈0.12 mol
The number of moles of CO2 and O2 are 0.21 and 0.12 respectively.
Answer: 0.21 and 0.12