The internal energy of a gas is given by U=nCVT.
A diatomic gas has 3 translational and 2 rotational degrees of freedom. A monoatomic gas has 3 translational degrees of freedom.
Hence, the internal energy of the mixture =n1CV1T+n2CV2T
=2×(25R)T+4×23RT=5RT+6RT
=11RT