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The rate of reaction 2 ~N_2 O_5 longrightarrow 4 NO_2+ O_2 can be written in three ways … The relationship betweenkandk^{\prime}and…

NEET UG 2011 — Chemistry Physical Chemistry

2011mcqmedium

The rate of reaction 2 N2O5⟶4NO2+O22 \mathrm{~N}_2 \mathrm{O}_5 \longrightarrow 4 \mathrm{NO}_2+\mathrm{O}_22 N2​O5​⟶4NO2​+O2​ can be written in three ways −d[ N2O5]dt=k[ N2O5]d[NO2]dt=k′[N2O5]d[O2]dt=k′′[N2O5]\begin{aligned} \frac{-d\left[\mathrm{~N}_2 \mathrm{O}_5\right]}{d t} & =k\left[\mathrm{~N}_2 \mathrm{O}_5\right] \\ \frac{d\left[\mathrm{NO}_2\right]}{d t} & =k^{\prime}\left[\mathrm{N}_2 \mathrm{O}_5\right] \\ \frac{d\left[\mathrm{O}_2\right]}{d t} & =k^{\prime \prime}\left[\mathrm{N}_2 \mathrm{O}_5\right] \end{aligned}dt−d[ N2​O5​]​dtd[NO2​]​dtd[O2​]​​=k[ N2​O5​]=k′[N2​O5​]=k′′[N2​O5​]​ The relationship between kkk and k′k^{\prime}k′ and between kkk and k′′k^{\prime \prime}k′′ are

Official previous-year question

Held on 30 Apr 2011 · Verified 9 Jul 2026.

Options

  1. A

    k′=2k;k′=kk^{\prime}=2 k ; k^{\prime}=kk′=2k;k′=k

  2. B

    k′=2k;k′′=k/2k^{\prime}=2 k ; k^{\prime \prime}=k / 2k′=2k;k′′=k/2

  3. C

    k′=2k;k′′=2kk^{\prime}=2 k ; k^{\prime \prime}=2 kk′=2k;k′′=2k

  4. D

    k′=k;k′′=kk^{\prime}=k ; k^{\prime \prime}=kk′=k;k′′=k

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