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A solution contains Fe^2+, Fe^3+ and I^-ions. This solution was treated with iodine at 35° C. E° for Fe^3+ / Fe^2+ is +0.77 ~V and E° for I_2 / 2…

NEET UG 2011 — Chemistry Physical Chemistry

2011mcqmedium

A solution contains Fe2+,Fe3+\mathrm{Fe}^{2+}, \mathrm{Fe}^{3+}Fe2+,Fe3+ and I−\mathrm{I}^{-}I−ions. This solution was treated with iodine at 35∘C35^{\circ} \mathrm{C}35∘C. E∘E^{\circ}E∘ for Fe3+/Fe2+\mathrm{Fe}^{3+} / \mathrm{Fe}^{2+}Fe3+/Fe2+ is +0.77 V+0.77 \mathrm{~V}+0.77 V and E∘\mathrm{E}^{\circ}E∘ for I2/2I−=0.536 V\mathrm{I}_2 / 2 \mathrm{I}^{-}=0.536 \mathrm{~V}I2​/2I−=0.536 V. The favourable redox reaction is

Official previous-year question

Held on 30 Apr 2011 · Verified 9 Jul 2026.

Options

  1. A

    I2\mathrm{I}_2I2​ will be reduced to I−\mathrm{I}^{-}I−

  2. B

    There will be no redox reaction

  3. C

    I−\mathrm{I}^{-}I−will be oxidised to I2\mathrm{I}_2I2​

  4. D

    Fe2+\mathrm{Fe}^{2+}Fe2+ will be oxidised to Fe3+\mathrm{Fe}^{3+}Fe3+

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