Acetone on reaction with methyl magnesium bromide gives tertiary alcohol.
In this reaction methyl carbanion attacks on carbonyl compound on the electrophilic site of carbonyl group to form tertiary alcohol.

NEET UG 2020 — Chemistry Organic Chemistry
Reaction between acetone and methylmagnesium chloride followed by hydrolysis will give:
Held on 30 Apr 2020 · Verified 9 Jul 2026.
Sec. butyl alcohol
Tert. butyl alcohol
Isobutyl alcohol
Isopropyl alcohol
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Markovnikov's rule is applicable to:
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