
(i) Na/ Liquid NH3 (Birch reduction) it reduces non-terminal alkynes into alkene (trans/anti addition)
(ii) H2/Pd−C, quinoline (lindlar catalyst) reduces alkyne into alkene by syn addition. This will give the required product.
(iii) Zn/HCl is Clemmensen reduction which reduced carbonyl into an alkene.
(iv) Hg+2/H⊕,H2O is an electrophilic addition reaction, which converts alkyne into ketone.
