Key Idea Ionisation energy usually increases from left to right in a period with decrease in atomic size and decreases from upto down in a group with increase in atomic size. Electronic configuration [Ne]3 s23p3[Ne]3 s23p2[Ar]3 d10,4 s2,4p3[Ne]3 s23p1 Group V IV V III Since IE increases in a period and decreases in a group, [Ne] 3s23p3 configuration has the highest ionisation energy among the given.