
For polybasic acid, order of ionization constant is Ka1>Ka2>Ka3 because as negative charge increases, tendency to loose H+ions decreases. Overall K=Ka1×Ka2×Ka3 Taking log on both sides logK=logKa1+logKa2+logKa3
NEET UG 2025 — Chemistry Physical Chemistry
Phosphoric acid ionizes in three steps with their ionization constant values Ka1, Ka2 and Ka3, respectively, While K is the overall ionization constant. Which of the following statements are true? A. logK=logKa1+logKa2+logKa3 B. H3PO4 is a stronger acid than H2PO4−and HPO42− C. Ka1>Ka2>Ka3 D. Ka1=2Ka3+Ka2 Choose the correct answer from the options given below:
Held on 30 Apr 2025 · Verified 9 Jul 2026.
A and B only
A and C only
B,C and D only
A, B and C only
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For the reaction 2SO₂(g) + O₂(g) ⇌ 2SO₃(g), ΔH = -198 kJ. Which condition favours forward reaction?
The unit of rate constant for a first-order reaction is:
Among the following choose the ones with equal number of atoms. A. 212 g of $\mathrm{Na}_2 \mathrm{CO}_3(\mathrm{~s})$ [molar mass $=106 \mathrm{~g}$ ] B. 248 g of $\mathrm{Na}_2 \mathrm{O}$ (s) [molar mass $=62 \mathrm{~g}$ ] C. 240 g of $\mathrm{NaOH}(\mathrm{s})$ [molar mass $=40 \mathrm{~g}]$ D. 12 g of $\mathrm{H}_2(\mathrm{~g})$ [molar mass $=2 \mathrm{~g}$ ] E. 220 q of $\mathrm{CO}_2(\mathrm{q})$ [molar mass $\left.=44 \mathrm{~g}\right]$ Choose the correct answer from the options given below:
For the reaction $\mathrm{A}(\mathrm{g}) \rightleftharpoons 2 \mathrm{~B}(\mathrm{~g})$, the backward reaction rate constant is higher than the forward reaction rate constant by a factor of 2500 , at 1000 K . [Given : $\mathrm{R}=0.0831 \mathrm{~L} \mathrm{~atm} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}$ ] $\mathrm{K}_{\mathrm{p}}$ for the reaction at 1000 K is
The standard heat of formation, in $\mathrm{kcal} / \mathrm{mol}^{\text {of }} \mathrm{Ba}^{2+}$ is : [Given : standard heat of formation of $\mathrm{SO}_4^{2-}$ ion (aq) $=-216 \mathrm{kcal} / \mathrm{mol}$, Standard heat of crystallisation of $\mathrm{BaSO}_4(\mathrm{~s})=-4.5 \mathrm{kcal} / \mathrm{mol}$, standard heat of formation of $\left.\mathrm{BaSO}_4(\mathrm{~s})=-349 \mathrm{kcal} / \mathrm{mol}\right]$
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