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Consider the following liquid - vapour equilibrium. Liquid⇌ Vapour Which of the following relations is correct?

NEET UG 2016 — Chemistry Physical Chemistry

2016mcqhard

Consider the following liquid - vapour equilibrium.

Liquid⇌VapourLiquid\rightleftharpoons VapourLiquid⇌Vapour

Which of the following relations is correct?

Official previous-year question

Held on 30 Apr 2016 · Verified 9 Jul 2026.

Options

  1. A

    dlnGdT2=ΔHυRT2\frac{d\mathrm{ln}G}{d{T}^{2}}=\frac{\Delta {H}_{\upsilon }}{R{T}^{2}}dT2dlnG​=RT2ΔHυ​​

  2. B

    dlnPdT=−ΔHυRT\frac{d\mathrm{ln}P}{dT}=\frac{-\Delta {H}_{\upsilon }}{RT}dTdlnP​=RT−ΔHυ​​

  3. C

    dlnPdT2=−ΔHυT2\frac{d\mathrm{ln}P}{d{T}^{2}}=\frac{-\Delta {H}_{\upsilon }}{{T}^{2}}dT2dlnP​=T2−ΔHυ​​

  4. D

    dlnPdT=ΔHυRT2\frac{d\mathrm{ln}P}{dT}=\frac{\Delta {H}_{\upsilon }}{R{T}^{2}}dTdlnP​=RT2ΔHυ​​

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