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The reaction of hydrogen and iodine monochloride is given as: H_2(g)+2 ICl_(g) → 2 HCl_(g)+ I_2(g) This reaction is of first order with respect to…

NEET UG 2007 — Chemistry Physical Chemistry

2007mcqeasy

The reaction of hydrogen and iodine monochloride is given as: H2(g)+2ICl(g)→2HCl(g)+I2(g)\mathrm{H}_{2(g)}+2 \mathrm{ICl}_{(g)} \rightarrow 2 \mathrm{HCl}_{(g)}+\mathrm{I}_{2(g)}H2(g)​+2ICl(g)​→2HCl(g)​+I2(g)​ This reaction is of first order with respect to H2(g)\mathrm{H}_{2(g)}H2(g)​ and lCl(g)+\mathrm{lCl}_{(g)+}lCl(g)+​ following mechanisms were proposed Mechanism A: H2(g)+2ICl(g)→2HCl(g)+H2(g)\mathrm{H}_{2(g)}+2 \mathrm{ICl}_{(g)} \rightarrow 2 \mathrm{HCl}_{(g)}+\mathrm{H}_{2(g)}H2(g)​+2ICl(g)​→2HCl(g)​+H2(g)​ Mechanism B: H2(g)+ICl(g)→HCl(g)+HI(g) :slow Hl(g)+lCl(g)→HCl(g)+l2(g); fast \begin{aligned} & \mathrm{H}_{2(g)}+\mathrm{ICl}_{(g)} \rightarrow \mathrm{HCl}_{(g)}+\mathrm{HI}_{(g)} \text { :slow } \\ & \mathrm{Hl}_{(g)}+\mathrm{lCl}_{(g)} \rightarrow \mathrm{HCl}_{(g)}+\mathrm{l}_{2(g)} \text {; fast } \end{aligned}​H2(g)​+ICl(g)​→HCl(g)​+HI(g)​ :slow Hl(g)​+lCl(g)​→HCl(g)​+l2(g)​; fast ​ Which of the above mechanism(s) can be consistent with the given information about the reaction?

Official previous-year question

Held on 30 Apr 2007 · Verified 9 Jul 2026.

Options

  1. A

    A and B both

  2. B

    neither A nor B

  3. C

    A only

  4. D

    B only

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