For the cell reaction Fe+2Fe3+→3Fe2+ Anode reaction is Fe→Fe2++2e−Cathode reaction in 2Fe3++2e−→2Fe2+ECell∘=ECathode ∘−EAnode ∘=0.771−(−0.441)ECell∘=1.212 V Related Theory If the cell potential is negative, the reaction is reversed. In this case, the electrode of the galvanic cell should be written in a reversed order. Caution The positive potential indicates a spontaneous reaction