Type of isomerism exhibited by compounds [Cr(H2O)6]Cl3,[Cr(H2O)5ClClCl2⋅H2O,[Cr(H2O)4Cl2]Cl2.H2O\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3,\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_5 \mathrm{Cl}^{\mathrm{Cl}} \mathrm{Cl}_2 \cdot \mathrm{H}_2 \mathrm{O},\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_4 \mathrm{Cl}_2\right] \mathrm{Cl}_2 . \mathrm{H}_2 \mathrm{O}\right.[Cr(H2O)6]Cl3,[Cr(H2O)5ClClCl2⋅H2O,[Cr(H2O)4Cl2]Cl2.H2O and the value of coordination number (CN)(\mathrm{CN})(CN) of central metal ion in all these compounds, respectively is:
Held on 30 Apr 2023 · Verified 9 Jul 2026.
Ionisation isomerism, CN=4\mathrm{CN}=4CN=4
Solvate isomerism, CN=6\mathrm{CN}=6CN=6
Geometrical isomerism, CN=4\mathrm{CN}=4CN=4
Optical isomerism, CN=4\mathrm{CN}=4CN=4
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Solvate isomerism differ by whether or not a solvent molecule is directly bonded to the metal ion or merely present as free solvent molecules in the crystal lattice. - [Cr(H2O)6]Cl3,[Cr(H2O)5ClICl2.H2O\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3,\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_5 \mathrm{ClICl}_2 . \mathrm{H}_2 \mathrm{O}\right.[Cr(H2O)6]Cl3,[Cr(H2O)5ClICl2.H2O and [Cr(H2O)4Cl2]Cl22H2O\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_4 \mathrm{Cl}_2\right] \mathrm{Cl}_2 2 \mathrm{H}_2 \mathrm{O}[Cr(H2O)4Cl2]Cl22H2O show solvate isomerism. - Co-ordination number of Cr=6\mathrm{Cr}=6Cr=6
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