(1) V2O5-(iii) Oxidation of SO2 in the manufacture of H2SO4 by contact process. (2) TiCl4+Al(CH3)3− (Ziegler-Natta catalyst)- (iv) Polymerisation of ethylene. (3) PdCl2− (i) Oxidation of ethyne to ethanal. (4) Nickel complexes-(ii) Polymerisation of alkynes. Thus, the correct match is (1) → (iii), (2) → (iv), (3) → (i), (4) → (ii)
