(i) IBr2−

number of the electron in the valence shell =7+7+7+1=22
(ii) BeCl2

sp3d hybridised (linear).
Number of the electron in the valence shell =2+7+7=16
(iii) XeF2

number of electron in valence shell =8+7+7=22
(iv) TeI2

number of the electron in the valence shell = 6+7+7=24
(v) IF3

number of the electron in the valence shell =7+7+7+7=28
IBr2− and XeF2 both are isostructural and isoelectronic.