V2+(21)[Ar]183d34s0 Cr2+ (22) [Ar]183d44s0 Mn2+ (23) [Ar]183d54s0 Fe2+(24)[Ar]183d54s1 
The value of the third ionization enthalpy will be the largest in the case of manganese as the electrons in the orbitals are in half-filled stable electronic configuration and a very large amount of energy is required to overcome this effect.