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Organic Chemistry PYQ — Page 53

JEE Main Chemistry — Organic Chemistry previous year questions with solutions.

All Organic Chemistry Questions (1783)

Consider the following reactions, ![JEE Main 2020 Chemistry, Amines — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Amines/648b5a69417cc3fb48d66ddd/question_1__q_648b5a69417cc3fb48d66ddd__cdn-question-pool.getmarks.app__665e48c4-42bb-473f-ba4a-139c0a95bd5b__09d9148224_final_ppt_sync.jpeg) The compound $[P]$ is:

2020
hard
mcq

Among the following compounds, which one has the shortest $C–\mathrm{Cl}$ bond?

2020
medium
mcq

Which of the following reactions will not produce a racemic product ?

2020
medium
mcq

Which of the following compounds will show retention in configuration on nucleophile substitution by ${\mathrm{OH}}^{-}\mathrm{ion}$ ?

2020
medium
mcq

The decreasing order of reactivity of the following compounds towards nucleophilic substitution (${S}_{N}2$) is: ![JEE Main 2020 Chemistry, Haloalkanes and Haloarenes — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Haloalkanes_and_Haloarenes/648b5a68417cc3fb48d66a65/question_1__q_648b5a68417cc3fb48d66a65__cdn-question-pool.getmarks.app__e55c559b-1e96-4ccc-b91a-ed1ebda23518-image__4cc2c5f0a1_final_ppt_sync.png)

2020
medium
mcq

Arrange the following compounds in increasing order of $C-OH$ bond length: methanol, phenol, $p$ -ethoxyphenol

2020
medium
mcq

Which of the following has the shortest $C-Cl$ bond?

2020
medium
mcq

The correct order of stability for the following alkoxides is: ![JEE Main 2020 Chemistry, General Organic Chemistry — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/General_Organic_Chemistry/648b5a68417cc3fb48d66cb5/question_1__q_648b5a68417cc3fb48d66cb5__cdn-question-pool.getmarks.app__0f710e4e-38e3-45ba-bf30-fdd1a7e391ab-image__756756f331_final_ppt_sync.png)

2020
easy
mcq

The major product in the following reaction is : ![JEE Main 2020 Chemistry, Hydrocarbons — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Hydrocarbons/648b5a67417cc3fb48d6697e/question_1__q_648b5a67417cc3fb48d6697e__cdn-question-pool.getmarks.app__dad10317-0b0c-4568-9794-f73f2f9b6ee5-image__b2f9883fc6_final_ppt_sync.png)

2020
medium
mcq

The most suitable reagent for the given conversion is: ![JEE Main 2020 Chemistry, Carboxylic Acid Derivatives — question figure 1](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Carboxylic_Acid_Derivatives/648b5a68417cc3fb48d66d07/question_1__q_648b5a68417cc3fb48d66d07__cdn-question-pool.getmarks.app__92f6f7a9-a778-4fc3-bfd1-89e7c8954202__ac001a670a_final_ppt_sync.jpeg) ![JEE Main 2020 Chemistry, Carboxylic Acid Derivatives — question figure 2](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Carboxylic_Acid_Derivatives/648b5a68417cc3fb48d66d07/question_2__q_648b5a68417cc3fb48d66d07__cdn-question-pool.getmarks.app__f995b416-bb9c-4314-9f0d-2c5280db2ce7__6edbf074f5_final_ppt_sync.jpeg)

2020
easy
mcq

The increasing order of the boiling points of the major products $A,B$ and $C$ of the following reactions will be : (a) ![JEE Main 2020 Chemistry, Haloalkanes and Haloarenes — question figure 1](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Haloalkanes_and_Haloarenes/648b5a68417cc3fb48d66c2c/question_1__q_648b5a68417cc3fb48d66c2c__cdn-question-pool.getmarks.app__927c1392-7fbd-48c4-a648-ec5cb684f47d-image__04a2f817ee_final_ppt_sync.png) (b) ![JEE Main 2020 Chemistry, Haloalkanes and Haloarenes — question figure 2](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Haloalkanes_and_Haloarenes/648b5a68417cc3fb48d66c2c/question_2__q_648b5a68417cc3fb48d66c2c__cdn-question-pool.getmarks.app__b9264b96-6ee4-4ff1-ac42-cd6fa72f6b3e-image__996911364c_final_ppt_sync.png) (c) ![JEE Main 2020 Chemistry, Haloalkanes and Haloarenes — question figure 3](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Haloalkanes_and_Haloarenes/648b5a68417cc3fb48d66c2c/question_3__q_648b5a68417cc3fb48d66c2c__cdn-question-pool.getmarks.app__29156e6b-27e4-426f-9f65-19bc9fc70ec0-image__0d21b1dee9_final_ppt_sync.png)

2020
medium
mcq

The correct observation in the following reaction is: $\mathrm{Sucrose}\rightarrow _{\mathrm{Cleavage}(\mathrm{Hydrolysis})}^{\mathrm{Gly}\mathrm{cosidic}\mathrm{bond}}A+B\rightarrow _{\mathrm{Reagent}}^{\mathrm{Seliw}\mathrm{anoff}}?$

2020
medium
mcq

An organic compound [A], molecular formula ${C}_{10}{H}_{20}{O}_{2}$ was hydrolyzed with dilute sulphuric acid to given a carboxylic acid [B] and an alcohol [C]. Oxidation of [C] with ${\mathrm{CrO}}_{3}-{H}_{2}{\mathrm{SO}}_{4}$ produced [B]. Which of the following structures are not possible for $[A]$

2020
hard
mcq

The increasing order of ${\mathrm{pK}}_{b}$ values of the following compounds is : ![JEE Main 2020 Chemistry, Amines — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Amines/648b5a68417cc3fb48d66bdb/question_1__q_648b5a68417cc3fb48d66bdb__cdn-question-pool.getmarks.app__d8bf8ae0-ec52-4dd3-99ce-8264fa9f78ac-image__dc0b01273c_final_ppt_sync.png)

2020
medium
mcq

The increasing order of basicity of the following compounds is : ![JEE Main 2020 Chemistry, Amines — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Amines/648b5a68417cc3fb48d66b47/question_1__q_648b5a68417cc3fb48d66b47__cdn-question-pool.getmarks.app__d085f518-e567-424e-9589-c189cde8a843-image__e721c1be41_final_ppt_sync.png)

2020
medium
mcq

Which one of the following statement is not true?

2020
medium
mcq

The decreasing order of reactivity of the following organic molecules towards ${\mathrm{AgNO}}_{3}$ solution is: ![JEE Main 2020 Chemistry, General Organic Chemistry — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/General_Organic_Chemistry/648b5a68417cc3fb48d66ab6/question_1__q_648b5a68417cc3fb48d66ab6__cdn-question-pool.getmarks.app__ec08f4a0-3106-487a-8f8e-5433ded990d4-image__0cad56b0f9_final_ppt_sync.png)

2020
medium
mcq

The final major product of the following reaction is : ![JEE Main 2020 Chemistry, Hydrocarbons — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Hydrocarbons/648b5a68417cc3fb48d66b85/question_1__q_648b5a68417cc3fb48d66b85__cdn-question-pool.getmarks.app__bcb81f86-3416-430d-8317-eeb9d372a5b4-image__26e5e0942f_final_ppt_sync.png)

2020
medium
mcq

The increasing order of the following compounds towards $\mathrm{HCN}$ addition is : (i) ![JEE Main 2020 Chemistry, General Organic Chemistry — question figure 1](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/General_Organic_Chemistry/648b5a67417cc3fb48d6697f/question_1__q_648b5a67417cc3fb48d6697f__cdn-question-pool.getmarks.app__80c642c8-39c0-481f-a7bc-1f845903db14-image__3ef4137665_final_ppt_sync.png) (ii) ![JEE Main 2020 Chemistry, General Organic Chemistry — question figure 2](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/General_Organic_Chemistry/648b5a67417cc3fb48d6697f/question_2__q_648b5a67417cc3fb48d6697f__cdn-question-pool.getmarks.app__dd810336-14b8-41a8-a522-7ce53313b40f-image__4bdbaf599f_final_ppt_sync.png) (iii)![JEE Main 2020 Chemistry, General Organic Chemistry — question figure 3](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/General_Organic_Chemistry/648b5a67417cc3fb48d6697f/question_3__q_648b5a67417cc3fb48d6697f__cdn-question-pool.getmarks.app__93fdaff5-0d69-4223-be18-7fc77f444cc4-image__2849178ad9_final_ppt_sync.png)(iv) ![JEE Main 2020 Chemistry, General Organic Chemistry — question figure 4](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/General_Organic_Chemistry/648b5a67417cc3fb48d6697f/question_4__q_648b5a67417cc3fb48d6697f__cdn-question-pool.getmarks.app__06cee689-15e6-4068-824c-dafc089d581e-image__f74adc1bf3_final_ppt_sync.png)

2020
medium
mcq

The major product in the following reaction is: ![JEE Main 2020 Chemistry, Haloalkanes and Haloarenes — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Haloalkanes_and_Haloarenes/648b5a68417cc3fb48d66a6c/question_1__q_648b5a68417cc3fb48d66a6c__cdn-question-pool.getmarks.app__0a29d284-b85d-42eb-87bb-7f2f56cc045c-image__a6fa272ee2_final_ppt_sync.png)

2020
medium
mcq

In the following reaction $A$ is ![JEE Main 2020 Chemistry, Aldehydes and Ketones — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Aldehydes_and_Ketones/648b5a69417cc3fb48d66de4/question_1__q_648b5a69417cc3fb48d66de4__cdn-question-pool.getmarks.app__b6b8fb29-d94a-4824-80c2-f195e9d7766c-image__50c342212b_final_ppt_sync.png)

2020
hard
mcq

What is the product of following reaction? ![JEE Main 2020 Chemistry, Aldehydes and Ketones — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Aldehydes_and_Ketones/648b5a68417cc3fb48d66c6c/question_1__q_648b5a68417cc3fb48d66c6c__cdn-question-pool.getmarks.app__71c0cc73-89f1-4887-ad31-a0d717114841-image__1c4eacd207_final_ppt_sync.png) ?

2020
medium
mcq

The number of $s{p}^{2}$ hybrid orbitals in a molecule of benzene is:

2020
easy
mcq

The mechanism of Sn1 reaction is given as: $R-X\longrightarrow {R}^{\oplus }{X}^{\ominus }\longrightarrow {R}^{\oplus }\|{X}^{\ominus }\overset{{Y}^{\ominus }}{\longrightarrow }R-Y+{X}^{\ominus } \mathrm{lon}\mathrm{pair}\mathrm{Solvent} \mathrm{Speparated}\mathrm{ion} \mathrm{pair}$ A student writes general characteristics based on the given mechanism as : (a) The reaction is favoured by weak nucleophiles. (b) ${R}^{\oplus }$ would be easily formed if the substituents are bulky $y$ (c) The reaction is accompanied by recemization (d) The reaction is favoured by non-polar solvents. Which observations are correct?

2020
medium
mcq