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Organic Chemistry PYQ — Page 65

JEE Main Chemistry — Organic Chemistry previous year questions with solutions.

All Organic Chemistry Questions (1783)

![JEE Main 2014 Chemistry, Hydrocarbons — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Hydrocarbons/648b5a64417cc3fb48d65e51/question_1__q_648b5a64417cc3fb48d65e51__cdn-question-pool.getmarks.app__8DsvACR5WsEnShWPecrNZ9CCcZpo5Pe_Z9t2wbCpae4.original.fullsiz__4b37fabd19_final_ppt_sync.png) on mercuration-demercuration produces the major product:

2014
medium
mcq

The reagent needed for converting ![JEE Main 2014 Chemistry, Hydrocarbons — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Hydrocarbons/648b5a64417cc3fb48d65df8/question_1__q_648b5a64417cc3fb48d65df8__cdn-question-pool.getmarks.app__G_1xduRpEnG3M634kxnciZ_piMNeEOlPFJgcz9QKsoc.original.fullsiz__c99cea9c65_final_ppt_sync.png)

2014
medium
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The major product obtained in the photo catalysed bromination of 2-methylbutane is:

2014
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In the hydroboration - oxidation reaction of propene with diborane, ${H}_{2}{O}_{2}$ and $\mathrm{NaOH},$ the organic compound formed is:

2014
medium
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The correct IUPAC name of the following compound ![JEE Main 2014 Chemistry, General Organic Chemistry — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/General_Organic_Chemistry/648b5a64417cc3fb48d65eaa/question_1__q_648b5a64417cc3fb48d65eaa__cdn-question-pool.getmarks.app__EM0026263_Quest_1__292958d21c_final_ppt_sync.jpg) is :

2014
easy
mcq

In the presence of peroxide, $\mathrm{HCl}$ and $\mathrm{HI}$ do not give anti-Markownikoff's addition of alkenes because:

2014
medium
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The gas liberated by the electrolysis of Dipotassium succinate solution is:

2014
medium
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Which one of the following acids does not exhibit optical isomerism?

2014
medium
mcq

What is the product "C" after following reactions - ![JEE Main 2014 Chemistry, Alcohols Phenols and Ethers — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Alcohols_Phenols_and_Ethers/648b5a64417cc3fb48d65d47/question_1__q_648b5a64417cc3fb48d65d47__cdn-question-pool.getmarks.app__EM0025775_Quest_1__80d69a7198_final_ppt_sync.jpg)

2014
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The major product of the reaction is ![JEE Main 2014 Chemistry, Amines — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Amines/648b5a64417cc3fb48d65d99/question_1__q_648b5a64417cc3fb48d65d99__cdn-question-pool.getmarks.app__EM0025987_Quest_1__acab23b9d2_final_ppt_sync.jpg)

2014
hard
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For the estimation of nitrogen, $1.4g$ of an organic compound was digested by the Kjeldahl method and the evolved ammonia was absorbed in $60\mathrm{ml}$ of $\frac{ \text{M} }{ 1 0 }$ sulphuric acid. The unreacted acid required $20\mathrm{ml}$ of $\frac{ \text{M} }{ 1 0 }$ sodium hydroxide for complete neutralization. The percentage of nitrogen in the compound is

2014
hard
mcq

In a nucleophilic substitution reaction : $\text{R} - \text{Br} + {\text{Cl}}^{-} \overset{\text{DMF}}{\longrightarrow } \text{R} - \text{Cl} + {\text{Br}}^{-}$ , which one of the following undergoes complete inversion of configuration ?

2014
medium
mcq

Phthalic acid reacts with resorcinol in the presence of concentrated $\mathrm{H}_2 \mathrm{SO}_4$ to give:

2014
hard
mcq

In which of the following pairs $\text{A}$ is more stable than $\text{B?}$

2014
easy
mcq

Which one of the following bases is not present in DNA ?

2014
medium
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Considering the basic strength of amines in an aqueous solution, which one has the smallest ${\mathrm{pK}}_{b}$ value?

2014
easy
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Which one of the following reactions will not result in the formation of carbon-carbon bond ?

2014
medium
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The correct statement for the molecule ${\text{CsI}}_{3}$, is :

2014
easy
mcq

Allyl phenyl ether can be prepared by heating :

2014
medium
mcq

Conversion of benzene diazonium chloride to chlorobenzene is an example of which of the following reactions?

2014
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An organic compound $\mathrm{A}, \mathrm{C}_5 \mathrm{H}_8 \mathrm{O}$; reacts with $\mathrm{H}_2 \mathrm{O}, \mathrm{NH}_3$ and $\mathrm{CH}_3 \mathrm{COOH}$ as described below: ![JEE Main 2014 Chemistry, Aldehydes and Ketones — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Aldehydes_and_Ketones/648b5a64417cc3fb48d65dfa/question_1__q_648b5a64417cc3fb48d65dfa__cdn-question-pool.getmarks.app__AW2D_JyoZ2xrNPBt14lr6bAg9jXTnpP93Yij_Q1EixU.original.fullsiz__da9fdc6bbc_final_ppt_sync.png)

2014
hard
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Chlorobenzne reacts with trichloro acetaldehyde in the presence of $\mathrm{H}_2 \mathrm{SO}_4$. ![JEE Main 2014 Chemistry, Haloalkanes and Haloarenes — question figure](https://prepforbharat.s3.ap-south-1.amazonaws.com/exam/615f0e999476412f48314daf/Chemistry/images/Haloalkanes_and_Haloarenes/648b5a64417cc3fb48d65dfc/question_1__q_648b5a64417cc3fb48d65dfc__cdn-question-pool.getmarks.app__4PG8wRsi8DnPLsWg_wMUpu6WzQrEfBj3K44XSiDV58k.original.fullsiz__bea287e728_final_ppt_sync.png) The major product formed is:

2014
hard
mcq

For the compounds CH$_{3}$Cl, CH$_{3}$Br, CH$_{3}$I and CH$_{3}$F, the correct order of increasing C-halogen bond length is :

2014
medium
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Which of the following compounds will not be soluble in sodium bicarbonate?

2014
easy
mcq