The unit vector a makes angle 3π,4π and θ with \hat{i},\hat{j}&\hat{k} respectively.
Hence, the direction cosines of the vector a are cosα=cos3π=21,cosβ=cos4π=21 and cosγ=cosθ
For a line having direction cosines as cosα,cosβ,cosγ
⇒cos2α+cos2β+cos2γ=1
⇒41+21+cos2θ=1
⇒cos2θ=1−43=41
⇒cos2θ=±21
⇒θ=3π or 32π.