Circle C1 has radius 5 and chord on line y=x through origin.
Setting center at (5,0) (in region x≥0), the chord endpoints are (0,0) and (5,5) by solving (t−5)2+t2=25.
Circle C2 has this chord as diameter, so center is at (25,25) with radius 252.
The chord of C2 through (2,3) that is farthest from center is perpendicular to the radial direction from center to (2,3).
The radial direction is (2−25,3−25)=(−21,21) with normal direction (1,−1).
The chord equation is 1(x−2)−1(y−3)=0, giving x−y+1=0.
In form x+ay+b=0, we have a=−1 and b=1, so a−b=−1−1=−2.