Given,
The line y=−x bisect the chord PQ
If (λ,−λ) is the mid-point of the chord PQ then,
Q(2λ−α,−2λ−β)

Given circle 2x2+2y2−(1+a)x−(1−a)y=0
Or, x2+y2−(21+a)x−(21−a)y=0
Let 21+a=α,21−a=β
The circle equation will be,
x2+y2−αx−βy=0
Point Q will lie on the circle,
(2λ−α)2+(−2λ−β)2−α(2λ−α)−β(−2λ−β)=0
⇒4λ2+3λ(β−α)+(α2+β2)=0
So, quadratic in λ should have D>0
⇒9(β−α)2−4(4)(α2+β2)>0
Put the value of α and β we get,
⇒9a2−16(21+a2)>0
⇒a2>8