Correct Option (C)
From the given information, Q is explicitly stated as the brother of P. The term 'brother' unequivocally defines Q's gender as male. Therefore, Q is definitely a man.
Incorrect Options:
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P: P is identified as an unmarried student. The provided information does not contain any specific detail that determines P's gender. P could be either male or female.
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S: S is also identified as an unmarried student. Similar to P, there is no information provided that definitively establishes S's gender. S could be either male or female.
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None of the above: This option is incorrect because Q is definitively identified as a man based on the information that Q is P's brother.