Option 1 -> Imphal is correctly matched as the capital of Manipur.
Option 2 -> Thiruvananthapuram is correctly matched as the capital of Kerala.
Option 3 -> Aizawl is correctly matched as the capital of Mizoram.
Option 4 -> Amravati is wrongly matched with Telangana - Amravati is the capital of Andhra Pradesh, not Telangana.
Hence, Option 4: Telangana - Amravati -> The capital of Telangana is Hyderabad, not Amravati. Amravati is the planned capital of Andhra Pradesh (formed after the bifurcation of the state in 2014) -> correct